'Stunning' discovery: Metals can heal themselves

 

Scientists for the first time have witnessed pieces of metal crack, then fuse back together without any human intervention, overturning fundamental scientific theories in the process. If the newly discovered phenomenon can be harnessed, it could usher in an engineering revolution -- one in which self-healing engines, bridges and airplanes could reverse damage caused by wear and tear, making them safer and longer-lasting.

The research team from Sandia National Laboratories and Texas A&M University described their findings today in the journal Nature.

"This was absolutely stunning to watch first-hand," said Sandia materials scientist Brad Boyce.

"What we have confirmed is that metals have their own intrinsic, natural ability to heal themselves, at least in the case of fatigue damage at the nanoscale," Boyce said.

Fatigue damage is one way machines wear out and eventually break. Repeated stress or motion causes microscopic cracks to form. Over time, these cracks grow and spread until -- snap! The whole device breaks, or in the scientific lingo, it fails.

The fissure Boyce and his team saw disappear was one of these tiny but consequential fractures -- measured in nanometers.

"From solder joints in our electronic devices to our vehicle's engines to the bridges that we drive over, these structures often fail unpredictably due to cyclic loading that leads to crack initiation and eventual fracture," Boyce said. "When they do fail, we have to contend with replacement costs, lost time and, in some cases, even injuries or loss of life. The economic impact of these failures is measured in hundreds of billions of dollars every year for the U.S."

Although scientists have created some self-healing materials, mostly plastics, the notion of a self-healing metal has largely been the domain of science fiction.

"Cracks in metals were only ever expected to get bigger, not smaller. Even some of the basic equations we use to describe crack growth preclude the possibility of such healing processes," Boyce said.

Unexpected discovery confirmed by theory's originator

In 2013, Michael Demkowicz -- then an assistant professor at the Massachusetts Institute of Technology's department of materials science and engineering, now a full professor at Texas A&M -- began chipping away at conventional materials theory. He published a new theory, based on findings in computer simulations, that under certain conditions metal should be able to weld shut cracks formed by wear and tear.

The discovery that his theory was true came inadvertently at the Center for Integrated Nanotechnologies, a Department of Energy user facility jointly operated by Sandia and Los Alamos national laboratories.

"We certainly weren't looking for it," Boyce said.

Khalid Hattar, now an associate professor at the University of Tennessee, Knoxville, and Chris Barr, who now works for the Department of Energy's Office of Nuclear Energy, were running the experiment at Sandia when the discovery was made. They only meant to evaluate how cracks formed and spread through a nanoscale piece of platinum using a specialized electron microscope technique they had developed to repeatedly pull on the ends of the metal 200 times per second.

Surprisingly, about 40 minutes into the experiment, the damage reversed course. One end of the crack fused back together as if it was retracing its steps, leaving no trace of the former injury. Over time, the crack regrew along a different direction.

Hattar called it an "unprecedented insight."

Boyce, who was aware of the theory, shared his findings with Demkowicz.

"I was very glad to hear it, of course," Demkowicz said. The professor then recreated the experiment on a computer model, substantiating that the phenomenon witnessed at Sandia was the same one he had theorized years earlier.

Their work was supported by the Department of Energy's Office of Science, Basic Energy Sciences; the National Nuclear Security Administration and the National Science Foundation.

A lot remains unknown about the self-healing process, including whether it will become a practical tool in a manufacturing setting.

"The extent to which these findings are generalizable will likely become a subject of extensive research," Boyce said. "We show this happening in nanocrystalline metals in vacuum. But we don't know if this can also be induced in conventional metals in air."

Yet for all the unknowns, the discovery remains a leap forward at the frontier of materials science.

"My hope is that this finding will encourage materials researchers to consider that, under the right circumstances, materials can do things we never expected," Demkowicz said.

Sandia National Laboratories is a multimission laboratory operated by National Technology and Engineering Solutions of Sandia LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy's National Nuclear Security Administration. Sandia Labs has major research and development responsibilities in nuclear deterrence, global security, defense, energy technologies and economic competitiveness, with main facilities in Albuquerque, New Mexico, and Livermore, California.