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A new kind of polymer membrane created by researchers at Georgia Tech could reshape how refineries process crude oil, dramatically reducing the energy and water required while extracting even more useful materials.
The so-called DUCKY polymers -- more on the unusual name in a minute -- are reported Oct. 16 in Nature Materials. And they're just the beginning for the team of Georgia Tech chemists, chemical engineers, and materials scientists. They also have created artificial intelligence tools to predict the performance of these kinds of polymer membranes, which could accelerate development of new ones.
The implications are stark: the initial separation of crude oil components is responsible for roughly 1% of energy used across the globe. What's more, the membrane separation technology the researchers are developing could have several uses, from biofuels and biodegradable plastics to pulp and paper products.
"We're establishing concepts here that we can then use with different molecules or polymers, but we apply them to crude oil because that's the most challenging target right now," said M.G. Finn, professor and James A. Carlos Family Chair in the School of Chemistry and Biochemistry.
Crude oil in its raw state includes thousands of compounds that have to be processed and refined to produce useful materials -- gas and other fuels, as well as plastics, textiles, food additives, medical products, and more. Squeezing out the valuable stuff involves dozens of steps, but it starts with distillation, a water- and energy-intensive process.
Researchers have been trying to develop membranes to do that work instead, filtering out the desirable molecules and skipping all the boiling and cooling.
"Crude oil is an enormously important feedstock for almost all aspects of life, and most people don't think about how it's processed," said Ryan Lively, Thomas C. DeLoach Jr. Professor in the School of Chemical and Biomolecular Engineering. "These distillation systems are massive water consumers, and the membranes simply are not. They're not using heat or combustion. They just use electricity. You could ostensibly run it off of a wind turbine, if you wanted. It's just a fundamentally different way of doing a separation."
What makes the team's new membrane formula so powerful is a new family of polymers. The researchers used building blocks called spirocyclic monomers that assemble together in chains with lots of 90-degree turns, forming a kinky material that doesn't compress easily and forms pores that selectively bind and permit desirable molecules to pass through. The polymers are not rigid, which means they're easier to make in large quantities. They also have a well-controlled flexibility or mobility that allows pores of the right filtering structure to come and go over time.
The DUCKY polymers are created through a chemical reaction that's easy to produce at a scale that would be useful for industrial purposes. It's a flavor of a Nobel Prize-winning family of reactions called click chemistry, and that's what gives the polymers their name. The reaction is called copper-catalyzed azide-alkyne cycloaddition -- abbreviated CuAAC and pronounced "quack." Thus: DUCKY polymers.
In isolation, the three key characteristics of the polymer membranes aren't new; it's their unique combination that makes them a novelty and effective, Finn said.
The research team included scientists at ExxonMobil, who discovered just how effective the membranes could be. The company's scientists took the crudest of the crude oil components -- the sludge left at the bottom after the distillation process -- and pushed it through one of the membranes. The process extracted even more valuable materials.
"That's actually the business case for a lot of the people who process crude oils. They want to know what they can do that's new. Can a membrane make something new that the distillation column can't?" Lively said. "Of course, our secret motivation is to reduce energy, carbon, and water footprints, but if we can help them make new products at the same time, that's a win-win."
Predicting such outcomes is one way the team's AI models can come into play. In a related study recently published in Nature Communications, Lively, Finn, and researchers in Rampi Ramprasad's Georgia Tech lab described using machine learning algorithms and mass transport simulations to predict the performance of polymer membranes in complex separations.
"This entire pipeline, I think, is a significant development. And it's also the first step toward actual materials design," said Ramprasad, professor and Michael E. Tennenbaum Family Chair in the School of Materials Science and Engineering. "We call this a 'forward problem,' meaning you have a material and a mixture that goes in -- what comes out? That's a prediction problem. What we want to do eventually is to design new polymers that achieve a certain target permeation performance."
Complex mixtures like crude oil might have hundreds or thousands of components, so accurately describing each compound in mathematical terms, how it interacts with the membrane, and extrapolating the outcome is "non-trivial," as Ramprasad put it.
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